Take both

Psv ml +400(1x) +0.5+101(2x)

Kiev ml +260(1x) pk/+0.5 -109(2x) Draw +225(.5x)

Psv is a Longshot but at home. Madrid is tough but this is a tight game game Psv could get a 1-0 win.

Kiev is longer imo but odds are lower cause city has no pedigree in this competition. Another lethargic display by city would be no shock. They struggle against these types of clubs.